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Examples
NH
3
NH
3
HCl
HCl
H
2
O
H
2
O
PCl
3
PCl
3
ClF
3
ClF
3
XeF
4
XeF
4
School of Chemistry
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VSEPR
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Lone Pairs
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Examples
> XeF
4
XeF
4
Central atom:
Xe
Xe contributes:
8 e
−
4 x F contibute:
4 e
−
Total VSE:
12
Total VSEP:
6
Geometry:
Square planar (based on octahedral)
Notes
F–Xe–F bond angles = 90 or 180°
Lone pairs are on opposite sides of the molecule (180° from each other) to minimise lone-pair:lone-pair interactions.
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3-D rotatable diagram
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