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Examples
NH
3
NH
3
HCl
HCl
H
2
O
H
2
O
PCl
3
PCl
3
ClF
3
ClF
3
XeF
4
XeF
4
School of Chemistry
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VSEPR
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Lone Pairs
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Examples
> PCl
3
PCl
3
Central atom:
P
P contributes:
5 e
−
3 x Cl contibute:
3 e
−
Total VSE:
8
Total VSEP:
4
Geometry:
Trigonal pyramidal (based on tetrahedral)
Note
Cl–P–Cl bond angle is less than 109° due to lone-pair:bonding-pair repulsion being greater than bonding-pair:bonding-pair repulsion
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3-D rotatable diagram
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