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NH
3
HCl
H
2
O
PCl
3
ClF
3
XeF
4
School of Chemistry
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VSEPR
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Lone Pairs
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Examples
> H
2
O
H
2
O
Central atom:
O
O contributes:
6 e
−
2 x H contibute:
2 e
−
Total VSE:
8
Total VSEP:
4
Geometry:
V-shaped (based on tetrahedral)
Note
H–O–H bond angle = 104.5° (less than 109° due to lone-pair:bonding-pair repulsion being greater than bonding-pair:bonding-pair repulsion)
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3-D rotatable diagram
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